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This work outlines conditions suitable for the heteroepitaxial growth of Cr2O3(0001) films (1.5–20 nm thick) on a Ru(0001)-terminated substrate. Optimized growth is achieved by sputter deposition of Cr within a 4 mTorr Ar/O2 20% ambient at Ru temperatures ranging from 450 to 600 °C. The Cr2O3 film adopts a 30° rotated honeycomb configuration with respect to the underlying Ru(0001) substrate and exhibits a hexagonal lattice parameter consistent with that for bulk Cr2O3(0001). Heating to 700 °C within the same environment during film preparation leads to Ru oxidation. Exposure to temperatures at or above 400 °C in a vacuum, Ar, or Ar/H2 3% leads to chromia film degradation characterized by increased Ru 3d XPS intensity coupled with concomitant Cr 2p and O 1s peak attenuations when compared to data collected from unannealed films. An ill-defined but hexagonally well-ordered RuxCryOz surface structure is noted after heating the film in this manner. Heating within a wet Ar/H2 3% environment preserves the Cr2O3(0001)/Ru(0001) heterolayer structure to temperatures of at least 950 °C. Heating an Ru–Cr2O3–Ru heterostacked film to 950 °C within this environment is shown by cross-sectional scanning/transmission electron microscopy (S/TEM) to provide clear evidence of retained epitaxial bicrystalline oxide interlayer structure, interlayer immiscibility, and epitaxial registry between the top and bottom Ru layers. Subtle effects marked by O enrichment and O 1s and Cr 2p shifts to increased binding energies are noted by XPS in the near-Ru regions of Cr2O3(0001)/Ru(0001) and Ru(0001)/Cr2O3(0001)/Ru(0001) films after annealing to different temperatures in different sets of environmental conditions. 

The science of volcanology advances disproportionately during exceptionally large or well-observed eruptions. The 2018 eruption of Kīlauea Volcano (Hawai‘i) was its most impactful in centuries, involving an outpouring of more than one cubic kilometer of basalt, a magnitude 7 flank earthquake, and the volcano's largest summit collapse since at least the nineteenth century. Eruptive activity was documented in detail, yielding new insights into large caldera-rift eruptions; the geometry of a shallow magma storage-transport system and its interaction with rift zone tectonics; mechanisms of basaltic tephra-producing explosions; caldera collapse mechanics; and the dynamics of fissure eruptions and high-volume lava flows. Insights are broadly applicable to a range of volcanic systems and should reduce risk from future eruptions. Multidisciplinary collaboration will be required to fully leverage the diversity of monitoring data to address many of the most important outstanding questions. ▪ Unprecedented observations of a caldera collapse and coupled rift zone eruption yield new opportunities for advancing volcano science. ▪ Magma flow to a low-elevation rift zone vent triggered quasi-periodic step-like collapse of a summit caldera, which pressurized the magma system and sustained the eruption. ▪ Kīlauea's magmatic-tectonic system is tightly interconnected over tens of kilometers, with complex feedback mechanisms and interrelated hazards over widely varying time scales. ▪ The eruption revealed magma stored in diverse locations, volumes, and compositions, not only beneath the summit but also within the volcano's most active rift zone. Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 52 is May 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates. 

Real-time monitoring is crucial to assess hazards and mitigate risks of sustained volcanic eruptions that last hours to months or more. Sustained eruptions have been shown to produce a low frequency (infrasonic) form of jet noise. We analyze the lava fountaining at fissure 8 during the 2018 Lower East Rift Zone eruption of Kīlauea volcano, Hawaii, and connect changes in fountain properties with recorded infrasound signals from an array about 500 m from the fountain using jet noise scaling laws and visual imagery. Video footage from the eruption reveals a change in lava fountain dynamics from a tall, distinct fountain at the beginning of June to a low fountain with a turbulent, out-pouring lava pond surrounded by a tephra cone by mid-June. During mid-June, the sound pressure level reaches a maximum, and peak frequency drops. We develop a model that uses jet noise scaling relationships to estimate changes in volcanic jet diameter and jet velocity from infrasound sound pressure levels and peak frequencies. The results of this model indicate a decrease in velocity in mid-June which coincides with the decrease in fountain height. Furthermore, the model results suggest an increase in jet diameter, which can be explained by the larger width of the fountain that resembles a turbulent lava pond compared to the distinct fountain at the beginning of June. The agreement between the infrasound-derived and visually observed changes in fountain dynamics suggests that jet noise scaling relationships can be used to monitor lava fountain dynamics using infrasound recordings.